QUEST Leibniz Research School

Synthesis of Novel Fullerene Complex

the [4+2] Cycloadduct of (Bicyclo[3.2.0]hepta-1,3-dienyl)cobalt(I) Complex with C₆₀

authored by: Masahiko Iyoda, Fatema Sultana, Shigeru Sasaki, Holger Butenschön
Abstract: The thermal reaction of C₆₀ with (η⁵-bicyclo[3.2.0]hepta-1,3-dienyl)(η⁴-tetraphenylcyclobutadiene)cobalt(I) produced the Diels-Alder adducts. The X-ray structural analysis of the 1:1 adduct revealed a novel molecular and crystal structure. An interesting redox behavior of the 1:1 adduct is described.
Organisation(s): Institute of Organic Chemistry
External Organisation(s): Tokyo Metropolitan University
Type: Article
Journal: Tetrahedron letters
Volume: 36
Pages: 579-582
No. of pages: 4
ISSN: 0040-4039
Publication date: 23.01.1995
Publication status: Published
Peer reviewed: Yes
ASJC Scopus subject areas: Biochemistry, Drug Discovery, Organic Chemistry
Electronic version(s): https://doi.org/10.1016/0040-4039(94)02257-C (Access: Unknown)

BibTeX

@article{6fa30eccacd24342aa090ecf8974d050,
title = "Synthesis of Novel Fullerene Complex: the [4+2] Cycloadduct of (Bicyclo[3.2.0]hepta-1,3-dienyl)cobalt(I) Complex with C60",
abstract = "The thermal reaction of C60 with (η5-bicyclo[3.2.0]hepta-1,3-dienyl)(η4-tetraphenylcyclobutadiene)cobalt(I) produced the Diels-Alder adducts. The X-ray structural analysis of the 1:1 adduct revealed a novel molecular and crystal structure. An interesting redox behavior of the 1:1 adduct is described.",
author = "Masahiko Iyoda and Fatema Sultana and Shigeru Sasaki and Holger Butensch{\"o}n",
note = "Funding information: Acknowledgement: We thank Prof. Y. Wakatsuki, the Institute of Physical & Chemical Research (Riken) for giving us the cobalt complex 1. We also thank Drs. H. Matsuyama and M. Yoshida, Tokyo Metropolitan University for helpful discussions. Financial support by a Grant-in-Aid for Scientific Research on Priority Areas from the Ministry of Education, Science and Culture, Japan (05233224) and the Fonds der Chemischen Industrie, Germany, is gratefully acknowledged.",
year = "1995",
month = jan,
day = "23",
doi = "10.1016/0040-4039(94)02257-C",
language = "English",
volume = "36",
pages = "579--582",
journal = "Tetrahedron letters",
issn = "0040-4039",
publisher = "Elsevier Ltd.",
number = "4",
}

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