A new type of high-temperature, high-pressure cell for spectroscopic studies of hydrous silicate melts

authored by
Marcus Nowak, Harald Behrens, Wilhelm Johannes
Abstract

A novel type of high-temperature, high-pressure cell has been designed for near-infrared and optical spectroscopy of hydrous silicate melts at pressures up to 3 kbar and temperatures up to 800°C. It consists of an externally heated cell with a disk-shaped sample chamber (4 mm in diameter and 0.2 mm in height) that is compressed between a tungsten carbide piston and a cylindrical sapphire window. A platinum ring surrounding the sample prevents loss of melt or water during the experiment. The new spectroscopic cell was used for direct measurement of H2O species in aluminosilicate melts by near-infrared spectroscopy. Other possible applications of the cell include the study of silicate melts doped with transition metal ions in the UV-VIS-NIR and the observation of the crystallization and dissolution of minerals in hydrous silicate melts under in situ conditions.

Organisation(s)
Institute of Mineralogy
External Organisation(s)
University of Bayreuth
Type
Article
Journal
American mineralogist
Volume
81
Pages
1507-1512
No. of pages
6
ISSN
0003-004X
Publication date
01.12.1996
Publication status
Published
Peer reviewed
Yes
ASJC Scopus subject areas
Geophysics, Geochemistry and Petrology
Electronic version(s)
https://doi.org/10.2138/am-1996-11-1222 (Access: Closed)