Enantioselective synthesis of polyketide segments through vinylogous Mukaiyama aldol reactions
- authored by
- Serkan Simsek, Markus Kalesse
- Abstract
The synthesis of polyketide segments through the vinylogous Mukaiyama aldol reaction is reported. The use of chiral oxazaborolidines allows using terminal substituted ketene acetals and provides access to extended segments and two new chiral centers.
- Organisation(s)
-
Institute of Organic Chemistry
- Type
- Article
- Journal
- Tetrahedron letters
- Volume
- 50
- Pages
- 3485-3488
- No. of pages
- 4
- ISSN
- 0040-4039
- Publication date
- 01.07.2009
- Publication status
- Published
- Peer reviewed
- Yes
- ASJC Scopus subject areas
- Biochemistry, Drug Discovery, Organic Chemistry
- Electronic version(s)
-
https://doi.org/10.1016/j.tetlet.2009.03.013 (Access:
Unknown)
