Structure, methyl internal rotation, centrifugal distortion, and dipole moment of 2-chloropropane

authored by: Michael Meyer, Jens Uwe Grabow, Helmut Dreizler, Heinz Dieter Rudolph
Abstract: The microwave spectra of six isotopic species of 2-chloropropane have been investigated by microwave Fourier transform spectoscopy. The quartic and some sextic centrifugal distortion constants of the ³⁵Cl and ³⁷Cl species are given. The structure has been derived by various methods. The dipole moment was found to be 2.141 D. From excited torsional states the parameters V₃ and V₁₂′ of the torsional potential function were obtained.
Organisation(s): Institute of Physical Chemistry and Electrochemistry
External Organisation(s): Kiel University
Ulm University
Type: Article
Journal: Journal of molecular spectroscopy
Volume: 151
Pages: 217-242
No. of pages: 26
ISSN: 0022-2852
Publication date: 01.1992
Publication status: Published
Peer reviewed: Yes
ASJC Scopus subject areas: Atomic and Molecular Physics, and Optics, Spectroscopy, Physical and Theoretical Chemistry
Electronic version(s): https://doi.org/10.1016/0022-2852(92)90017-I (Access: Unknown)