Structure-directed materials syntheses

Metal complexes as structure-directing agents for zeolite-type solids

authored by: Peter Behrens, Christian Panz, Volker Hufnagel, Benedikt Lindlar, Clemens C. Freyhardt, Gianpietro Van De Goor
Abstract: Metal complexes have been discovered as a novel class of structure-directing agents for the synthesis of porosils, i.e. zeolite-type solids with a pure silica framework. A survey is given about the different preparation methods used and the silica-metal complex host-guest compounds that have been synthesized so far. Special attention is given to differences between cobalticinium nonasil compounds that have been synthesized in basic or fluoride media.
External Organisation(s): Ludwig-Maximilians-Universität München (LMU)
Type: Article
Journal: SOLID STATE IONICS
Volume: 101-103
Pages: 229-234
No. of pages: 6
ISSN: 0167-2738
Publication date: 11.1997
Publication status: Published
Peer reviewed: Yes
ASJC Scopus subject areas: General Chemistry, General Materials Science, Condensed Matter Physics

BibTeX

@article{158d0505656245c9b6e3753bd6d43078,
title = "Structure-directed materials syntheses: Metal complexes as structure-directing agents for zeolite-type solids",
abstract = "Metal complexes have been discovered as a novel class of structure-directing agents for the synthesis of porosils, i.e. zeolite-type solids with a pure silica framework. A survey is given about the different preparation methods used and the silica-metal complex host-guest compounds that have been synthesized so far. Special attention is given to differences between cobalticinium nonasil compounds that have been synthesized in basic or fluoride media.",
keywords = "Clathrasils, Hydrothermal method, Structure-directed synthesis, Structure-directing agents, Zeosils",
author = "Peter Behrens and Christian Panz and Volker Hufnagel and Benedikt Lindlar and Freyhardt, {Clemens C.} and {Van De Goor}, Gianpietro",
note = "Funding information: Part of this work was carried out in the group of Prof. Felsche at the University of Konstanz. The work was supported by the Deutsche Forschungs-gemeinschaft (Be 1664/1-2), the Fonds der Chemischen Industrie and by a grant from the Riedel-de HaEn AG (Seelze, Germany). We also thank the 'Freunde und F6rderer der Ludwig-Max-imilians-Universit~it' for the generous gift of a polarization microscope.",
year = "1997",
month = nov,
language = "English",
volume = "101-103",
pages = "229--234",
journal = "SOLID STATE IONICS",
issn = "0167-2738",
publisher = "Elsevier",
number = "PART 1",
}