Very low surface recombination velocities on p - and n -type c-Si by ultrafast spatial atomic layer deposition of aluminum oxide

authored by
Florian Werner, Boris Veith, Veronica Tiba, Paul Poodt, Fred Roozeboom, Rolf Brendel, Jan Schmidt
Abstract

Using aluminum oxide (Al2 O3) films deposited by high-rate spatial atomic layer deposition (ALD), we achieve very low surface recombination velocities of 6.5 cm/s on p -type and 8.1 cm/s on n -type crystalline silicon wafers. Using spatially separated reaction zones instead of the conventional time-sequenced precursor dosing enables growth rates up to 70 nm/min, whereas conventional ALD limits the growth rate to <2 nm/min. The excellent passivation level is predominantly assigned to a high negative fixed charge density of Qf =- (4±1) × 1012 cm-2 in the Al2 O3 films. We demonstrate an excellent thermal stability of the passivation quality.

External Organisation(s)
Institute for Solar Energy Research (ISFH)
SoLayTec
Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek (TNO)
Eindhoven University of Technology (TU/e)
Type
Article
Journal
Applied physics letters
Volume
97
ISSN
0003-6951
Publication date
18.10.2010
Publication status
Published
Peer reviewed
Yes
ASJC Scopus subject areas
Physics and Astronomy (miscellaneous)
Electronic version(s)
https://doi.org/10.1063/1.3505311 (Access: Closed)