A mononuclear Fe(iii) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour
- authored by
- Terézia Bridová, Cyril Rajnák, Ján Titiš, Erika Samoľová, Kevin Tran, Ondřéj Malina, Alina Bieńko, Franz Renz, Milan Gembický, Roman Boča
- Abstract
AC susceptibility measurements of [FeIII(L5)(NCSe)] reveal a field supported slow magnetic relaxation. On cooling, the relaxation time of the high-frequency fraction decreases which is a sign of reciprocating thermal behaviour. The relaxation time for the low-frequency mode at T = 2.0 K is as high as τ(LF) = 2.0 s.
- Organisation(s)
-
Institute of Inorganic Chemistry
- External Organisation(s)
-
University of SS Cyril and Methodius, Trnava
Czech Academy of Sciences (CAS)
Palacky University
Technical University Ostrava
University of Wroclaw
University of California at San Diego
- Type
- Article
- Journal
- Dalton transactions
- Volume
- 53
- Pages
- 10824-10828
- No. of pages
- 5
- ISSN
- 1477-9226
- Publication date
- 04.06.2024
- Publication status
- Published
- Peer reviewed
- Yes
- ASJC Scopus subject areas
- Inorganic Chemistry
- Electronic version(s)
-
https://doi.org/10.1039/d4dt00642a (Access:
Closed)
