A mononuclear Fe(iii) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour
- verfasst von
- Terézia Bridová, Cyril Rajnák, Ján Titiš, Erika Samoľová, Kevin Tran, Ondřéj Malina, Alina Bieńko, Franz Renz, Milan Gembický, Roman Boča
- Abstract
AC susceptibility measurements of [FeIII(L5)(NCSe)] reveal a field supported slow magnetic relaxation. On cooling, the relaxation time of the high-frequency fraction decreases which is a sign of reciprocating thermal behaviour. The relaxation time for the low-frequency mode at T = 2.0 K is as high as τ(LF) = 2.0 s.
- Organisationseinheit(en)
-
Institut für Anorganische Chemie
- Externe Organisation(en)
-
University of SS Cyril and Methodius, Trnava
Akademie Věd České Republiky (AV ČR)
Palacky University
Technical University Ostrava
University of Wroclaw
University of California at San Diego
- Typ
- Artikel
- Journal
- Dalton transactions
- Band
- 53
- Seiten
- 10824-10828
- Anzahl der Seiten
- 5
- ISSN
- 1477-9226
- Publikationsdatum
- 04.06.2024
- Publikationsstatus
- Veröffentlicht
- Peer-reviewed
- Ja
- ASJC Scopus Sachgebiete
- Anorganische Chemie
- Elektronische Version(en)
-
https://doi.org/10.1039/d4dt00642a (Zugang:
Geschlossen)
