Lateral inhomogeneous boron segregation during silicon thin film growth with molecular beam epitaxy

verfasst von
D. Krüger, G. Lippert, R. Kurps, H. J. Osten
Abstract

Boron segregation from submonolayer (less than 0.1 monolayer) interfacial boron deposition during thin film silicon growth with molecular beam epitaxy (MBE) in the temperature range 450 to 800°C has been investigated by secondary ion mass spectrometry (SIMS) with high depth resolution abd lateral resolution of a few micrometer. Beginning at 600°C, segregation-induced "kinks" occur in the boron profiles developing into shoulders for higher growth temperatures and/or lower deposition rates. At temperatures above 700°C at the shoulder a concentration of (1-2) × 1019 cm-3 was found. Interfacial carbon showing significantly less segregation has been used as a marker. Laterally resolved SIMS measurements indicate inhomogeneous boron distribution, mainly due to residual substrate contamination. These inhomogeneities strongly influence the segregation behaviour, as shown by SIMS cross-section analysis, and can result in local boron penetration through multilayer structures, demonstrating the importance of appropriate cleaning procedures for residual boron substrate contamination.

Externe Organisation(en)
Leibniz-Institut für innovative Mikroelektronik (IHP)
Typ
Artikel
Journal
Journal of crystal growth
Band
135
Seiten
246-252
Anzahl der Seiten
7
ISSN
0022-0248
Publikationsdatum
01.1994
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Physik der kondensierten Materie, Anorganische Chemie, Werkstoffchemie
Elektronische Version(en)
https://doi.org/10.1016/0022-0248(94)90747-1 (Zugang: Geschlossen)