Novel Tricarbonyl(η⁴‐dihydroacepentalene)iron Complexes and Tricarbonyl(η²‐dihydroacepentalene)ferrates(−2)

authored by

Holger Butenschön, Armin de Meijere

Abstract

The first spectroscopically characterized (η²‐olefin)ferrates( – 2), 3, are formed on reduction of the novel (η⁴‐diene)iron complexes 2 with sodium. This reaction proceeds via a radical anion; high spin density at the iron is detected by ESR spectroscopy in the case of the reduction product of 2, NR₂ = piperidino. (Figure Presented.)

External Organisation(s)

Universität Hamburg

Type

Article

Journal

Angewandte Chemie International Edition in English

Volume

23

Pages

707-708

No. of pages

2

ISSN

0570-0833

Publication date

09.1984

Publication status

Published

Peer reviewed

Yes

ASJC Scopus subject areas

Catalysis, General Chemistry

Electronic version(s)

https://doi.org/10.1002/anie.198407071 (Access: Closed)
https://doi.org/10.1002/ange.19840960933 (Access: Closed)