Übergangsmetall-fulven-komplexe. XXVII. Basische fulven-komplexe
- authored by
- Frank Edelmann, Peter Behrens, Sabine Behrens, Ulrich Behrens
- Abstract
Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1 : 1 adducts. The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand. The first crystalline protonation product of a fulvene complex was obtained by treatment of [η5-6,6-bis(dimethylamino)fulvene]Cr(CO)3 with HBF4.
- External Organisation(s)
-
Universität Hamburg
- Type
- Article
- Journal
- Journal of Organometallic Chemistry
- Volume
- 309
- Pages
- 109-116
- No. of pages
- 8
- ISSN
- 0022-328X
- Publication date
- 1986
- Publication status
- Published
- Peer reviewed
- Yes
- ASJC Scopus subject areas
- Biochemistry, Physical and Theoretical Chemistry, Organic Chemistry, Inorganic Chemistry, Materials Chemistry
- Electronic version(s)
-
https://doi.org/10.1016/S0022-328X(00)99577-9 (Access:
Closed)
