Dihydroacepentalenediide, the Dianion of Acepentalene
- authored by
- Thomas Lendvai, Thomas Friedl, Holger Butenschön, Timothy Clark, Armin de Meijere
- Abstract
The long‐sought dianion of the still unknown acepentalene 2 is formed surprisingly easily upon reaction of triquinacene 1 with n‐butylithium and potassium tert‐amyl alkoxide in hexane at room temperature. 22⊖ reacts with chlorotrimethylsilane to give a mixture of 1,4‐ and 1,10‐bis(trimethylsilyl)dihydroacepentalenes. (Figure Presented.)
- External Organisation(s)
-
Universität Hamburg
Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU Erlangen-Nürnberg)
- Type
- Article
- Journal
- Angewandte Chemie International Edition in English
- Volume
- 25
- Pages
- 719-720
- No. of pages
- 2
- ISSN
- 0570-0833
- Publication date
- 08.1986
- Publication status
- Published
- Peer reviewed
- Yes
- ASJC Scopus subject areas
- Catalysis, General Chemistry
- Electronic version(s)
-
https://doi.org/10.1002/anie.198607191 (Access:
Closed)
https://doi.org/0.1002/ange.19860980817 (Access: Closed)
