Formation of a sulphur-sulphur bridged radical cation during the oxidation of 1,4-dithian by hydroxyl radicals

authored by

Detlef Bahnemann, Klaus Dieter Asmus

Abstract

A transient radical cation with a three-electron bond between the two sulphur atoms in the 1,4-positions is formed upon oxidation of 1,4-dithian by OH radicals in aqueous solutions at low solute concentration.

External Organisation(s)

Helmholtz-Zentrum Berlin für Materialien und Energie (HZB)

Type

Article

Journal

Journal of the Chemical Society, Chemical Communications

Pages

238-239

No. of pages

2

ISSN

0022-4936

Publication date

1975

Publication status

Published

Peer reviewed

Yes

ASJC Scopus subject areas

Molecular Medicine

Electronic version(s)

https://doi.org/10.1039/C39750000238 (Access: Unknown)