Spectroscopic investigations of novel host-guest compounds based on microporous SiO2 frameworks and inorganic guest species
- verfasst von
- G. Wirnsberger, H. P. Fritzer, G. Van De Goor, B. Pillep, Peter Behrens, A. Popitsch
- Abstract
The well-defined pore systems of crystalline microporous SiO2 modifications (porosils) can be used as templates for the ordered arrangement of inorganic guest species like iodine or the mercury halides. The systematic variation of the host structures, including pore systems from zero- to three-dimensional, allows interactions between the guest molecules in various directions to be controlled. Moreover, the periodic cage system of one of the porosils used, deca-dodecasil 3R, is well-suited as a crystalline matrix for the isolation of sulphur rings. The unique properties of these novel host-guest compounds are probed using spectroscopic techniques, including X ray absorption, UV/Vis and Raman spectroscopy.
- Externe Organisation(en)
-
Technische Universität Graz
Ludwig-Maximilians-Universität München (LMU)
Universität Graz
- Typ
- Artikel
- Journal
- Journal of molecular structure
- Band
- 410-411
- Seiten
- 123-127
- Anzahl der Seiten
- 5
- ISSN
- 0022-2860
- Publikationsdatum
- 16.06.1997
- Publikationsstatus
- Veröffentlicht
- Peer-reviewed
- Ja
- ASJC Scopus Sachgebiete
- Analytische Chemie, Spektroskopie, Organische Chemie, Anorganische Chemie
- Elektronische Version(en)
-
https://doi.org/10.1016/S0022-2860(96)09678-0 (Zugang:
Unbekannt)
