Construction of Carbon Frameworks with the Help of Ruthenium Complexes
1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions
- verfasst von
- Holger Butenschön
- Abstract
Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)
- Organisationseinheit(en)
-
Institut für Organische Chemie
- Typ
- Artikel
- Journal
- Angewandte Chemie International Edition in English
- Band
- 33
- Seiten
- 636-638
- Anzahl der Seiten
- 3
- ISSN
- 0570-0833
- Publikationsdatum
- 31.03.1994
- Publikationsstatus
- Veröffentlicht
- Peer-reviewed
- Ja
- ASJC Scopus Sachgebiete
- Katalyse, Allgemeine Chemie
- Elektronische Version(en)
-
https://doi.org/10.1002/anie.199406361 (Zugang:
Geschlossen)
https://doi.org/10.1002/ange.19941060607 (Zugang: Geschlossen)
