Nuclear magnetic and conductivity relaxations by Li diffusion in glassy and crystalline LiAlSi₄O₁₀

verfasst von: R. Winter, K. Siegmund, P. Heitjans
Abstract: The dependence of lithium diffusion on the degree of structural order was investigated in LiAlSi₄O₁₀ in its glassy and polycrystalline states by nuclear magnetic resonance (NMR) and ionic conductivity relaxation techniques. The NMR measurements were performed in the temperature range from 150 K to 1000 K, which covers the diffusion induced spin-lattice relaxation rate (T^-1₁) maximum for each of the modifications. The dependence of T^-1₁ on the Larmor frequency was observed in the range from 11.3 MHz to 38.9 MHz. Impedance spectroscopy was carried out on the glassy sample in the frequency interval from 100 Hz to 10 MHz and for temperatures between ambient temperature and 670 K. The results obtained from the two methods reflect significant deviations of the relaxation processes from their respective standard models (BPP and Debye) with regard to anomalous frequency dependences of T^-1₁ and of the conductivity, and a difference between the low and high temperature activation energies. These anomalies are discussed in terms of the dynamic structure model and other theories for anomalous relaxation in ionic conductors. When the results are analyzed in the framework of the dynamic structure model there are indications for clustering of the mobile species which results in correlated motion of Li ions. In a crystalline sample, the activation energy is larger and the jump frequency is smaller than in the amorphous material.
Organisationseinheit(en): Institut für Physikalische Chemie und Elektrochemie
Typ: Artikel
Journal: Journal of non-crystalline solids
Band: 212
Seiten: 215-224
Anzahl der Seiten: 10
ISSN: 0022-3093
Publikationsdatum: 06.1997
Publikationsstatus: Veröffentlicht
Peer-reviewed: Ja
ASJC Scopus Sachgebiete: Elektronische, optische und magnetische Materialien, Keramische und Verbundwerkstoffe, Physik der kondensierten Materie, Werkstoffchemie
Elektronische Version(en): https://doi.org/10.1016/S0022-3093(96)00654-0 (Zugang: Unbekannt)

BibTeX

@article{1ad7fe8896d8443599f3c087868ee34b,
title = "Nuclear magnetic and conductivity relaxations by Li diffusion in glassy and crystalline LiAlSi4O10",
abstract = "The dependence of lithium diffusion on the degree of structural order was investigated in LiAlSi4O10 in its glassy and polycrystalline states by nuclear magnetic resonance (NMR) and ionic conductivity relaxation techniques. The NMR measurements were performed in the temperature range from 150 K to 1000 K, which covers the diffusion induced spin-lattice relaxation rate (T-11) maximum for each of the modifications. The dependence of T-11 on the Larmor frequency was observed in the range from 11.3 MHz to 38.9 MHz. Impedance spectroscopy was carried out on the glassy sample in the frequency interval from 100 Hz to 10 MHz and for temperatures between ambient temperature and 670 K. The results obtained from the two methods reflect significant deviations of the relaxation processes from their respective standard models (BPP and Debye) with regard to anomalous frequency dependences of T-11 and of the conductivity, and a difference between the low and high temperature activation energies. These anomalies are discussed in terms of the dynamic structure model and other theories for anomalous relaxation in ionic conductors. When the results are analyzed in the framework of the dynamic structure model there are indications for clustering of the mobile species which results in correlated motion of Li ions. In a crystalline sample, the activation energy is larger and the jump frequency is smaller than in the amorphous material.",
author = "R. Winter and K. Siegmund and P. Heitjans",
note = "Funding Information: We thank Dr P. NaB, Schott Glaswerke, Mainz, for providing the glassy material and Dr G. Wolff and H. Nickel from the Zentralabteilung fOr chemi-sche Analysen, Forschungszentrum Jiilich GmbH, for the chemical analysis of the glass. We wish to thank Dr S.H. Chung, now National Institute for Research in Inorganic Materials, Tsukuba, Japan, and Dr G. Balzer, Institut fOr Anorganische Chemie, Universit~it Hannover, for helpful discussions. Financial support by the Deutsche Forschungsgemein-schaft (SFB 173) and the Fonds der Chemischen Industrie is gratefully acknowledged.",
year = "1997",
month = jun,
doi = "10.1016/S0022-3093(96)00654-0",
language = "English",
volume = "212",
pages = "215--224",
journal = "Journal of non-crystalline solids",
issn = "0022-3093",
publisher = "Elsevier",
number = "2-3",
}

Nuclear magnetic and conductivity relaxations by Li diffusion in glassy and crystalline LiAlSi4O10

Nuclear magnetic and conductivity relaxations by Li diffusion in glassy and crystalline LiAlSi₄O₁₀