Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the AlOSi bond angle in aluminosilicate sodalites

An empirical study

verfasst von
M. Fröba, J. Wong, P. Behrens, P. Sieger, M. Rowen, T. Tanaka, Z. Rek, J. Felsche
Abstract

Using a YB66 monochromator X-ray absorption measurements were carried out at the Al K and Si K absorption edges of a series of aluminosilicate sodalites. The AlOSi bridging angle of the selected sodalites varies from 138° to 148° and the structure of the XANES with its different multiple scattering (MS) features shows a strong angular dependence. Increasing the angle results in a decrease of the MS intensities. This dependence is especially pronounced at the Al K edges which contain a couple of separated well-resolved peaks whereas the corresponding features at the Si K edges are smeared out due to a strong overlapping of the peaks.

Externe Organisation(en)
Lawrence Livermore National Laboratory
Universität Konstanz
Stanford University
National Institute for Materials Science Tsukuba
Typ
Artikel
Journal
Physica B: Physics of Condensed Matter
Band
208-209
Seiten
65-67
Anzahl der Seiten
3
ISSN
0921-4526
Publikationsdatum
01.03.1995
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Elektronische, optische und magnetische Materialien, Physik der kondensierten Materie, Elektrotechnik und Elektronik
Elektronische Version(en)
https://doi.org/10.1016/0921-4526(94)00820-L (Zugang: Geschlossen)