Electric Quadrupole Interaction of ²⁰F in a KZnF₃ Single Crystal

verfasst von

H. Ackermann, D. Dubbers, M. Grupp, P. Heitjans, H. J. Stöckmann, K. P. Wanczek, K. Recker, R. Leckebusch

Abstract

Nuclear magnetic resonance measurements were carried out on neutron activated ²⁰F(T_1/2 = 11 s) nuclei in a single crystal of KZnF₃. The quadrupolar splitted NMR spectrum, detected via the ²⁰F β -radiation asymmetry, could be observed using a radio frequency modulation technique. The quadrupole coupling constant was determined to e²q Q/h= + (12.0 ± 1.5) MHz at room temperature. The sign of e² q Q was obtained from a simultaneous γ-ray anisotropy measurement on the succeeding ²⁰Ne transition. Utilising a calculated field gradient of the fluorine atom, an fq=4.6% is determined. This value is compared with literature data of similar compounds.

Externe Organisation(en)

Institut Laue-Langevin
Goethe-Universität Frankfurt am Main
Rheinische Friedrich-Wilhelms-Universität Bonn
Ruprecht-Karls-Universität Heidelberg

Typ

Artikel

Journal

Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences

Band

31

Seiten

1298-1302

Anzahl der Seiten

5

ISSN

0932-0784

Publikationsdatum

01.11.1976

Publikationsstatus

Veröffentlicht

Peer-reviewed

Ja

ASJC Scopus Sachgebiete

Mathematische Physik, Physik und Astronomie (insg.), Physikalische und Theoretische Chemie

Elektronische Version(en)

https://doi.org/10.1515/zna-1976-1105 (Zugang: Offen)