Stability and reliability of perovskite containing solar cells and modules

degradation mechanisms and mitigation strategies

verfasst von
Sara Baumann, Giles E. Eperon, Alessandro Virtuani, Quentin Jeangros, Dana B. Kern, Dounya Barrit, Jackson Schall, Wanyi Nie, Gernot Oreski, Mark Khenkin, Carolin Ulbrich, Robby Peibst, Joshua S. Stein, Marc Köntges
Abstract

Perovskite solar cells have shown a strong increase in efficiency over the last 15 years. With a record power conversion efficiency on small area above 34%, perovskite/silicon tandem solar cells already exceed the efficiency limit of silicon solar cells and their efficiency is expected to increase further. While predicted to take large markets shares in a few years thanks to their high efficiency and low manufacturing cost potential, perovskite/silicon tandem devices are not yet sufficiently reliable, which brings into question the commercial viability of this new technology. This review provides an extensive summary of degradation mechanisms occurring in perovskite solar cells and modules. In particular, instabilities triggered by the presence and generation of mobile ions in the perovskite absorber and/or by extrinsic stress factors are discussed in detail. In addition, mitigation strategies developed so far to improve the reliability of the technology are also presented.

Organisationseinheit(en)
Institut für Materialien und Bauelemente der Elektronik
Externe Organisation(en)
Institut für Solarenergieforschung GmbH (ISFH)
Swift Solar Inc.
CSEM SA
National Renewable Energy Laboratory
TotalEnergies
Colorado School of Mines (CSM)
Los Alamos National Laboratory
University of Leoben
Helmholtz-Zentrum Berlin für Materialien und Energie GmbH
Sandia National Laboratories NM
Typ
Übersichtsarbeit
Journal
Energy and Environmental Science
Band
17
Seiten
7566-7599
Anzahl der Seiten
34
ISSN
1754-5692
Publikationsdatum
02.08.2024
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Umweltchemie, Erneuerbare Energien, Nachhaltigkeit und Umwelt, Kernenergie und Kernkraftwerkstechnik, Umweltverschmutzung
Ziele für nachhaltige Entwicklung
SDG 7 – Erschwingliche und saubere Energie
Elektronische Version(en)
https://doi.org/10.1039/d4ee01898b (Zugang: Offen)